You only need to connect 24vdc to the field power and jumper to get 5v from the host card (5i25).
The field power only needs to be connected to the top (-) and bottom (+) pins.
The I/O is not configurable, so nothing needs to be done in PnC except tell it what does what.
Well it will be a DC on the step and direction pins, the direction pins might be easier to see with a meter.
The first thing I do is cycle the I/O to make sure each switch/prox/input is connected and working. Assuming your using Axis from the Machine menu open up the Show HAL Configuration window and put the I/O pins you have connected in a watch window. Then cycle each one to make sure they work. Then I usually move on to one drive at a time and make sure they move the correct amount and direction... then homing if there are limit/homing switches.
John